Rare
Earth: An Introduction
____________________________________________________________________
Entering
the 21st century, the pace of industrial and economic globalization
is speeding up. As China enters the WTO, the Chinese government
has begun the implementation of its policy to develop its western
regions. Located in western China, Baotou is famous for its rich
rare earth resources, thus being named "The Mother Lode of Rare
Earth". In 1992, Chinese President Deng Xiaoping pointed out,
"There is oil in the Middle East; there is rare earth in China¡."
That same year, the State Council approved the establishment
of the Baotou Rare Earth Hi-tech Industrial Development Zone.
During his 1999 visit to Baotou, President Jiang Zemin wrote,
"Improve the development and applications of rare earth, and change
the resource advantage into economic superiority." Then President
Jiang repeated the strategic importance
of developing China's rare earth industry, which has caught worldwide
attention.
The
reason why rare earth, a small industry with annual consumption
of only 75,000 tons REO and a market value below US$100 million,
has been given attention by Chinese leaders at all levels is due
to its uses in modern hi-tech industries because of its
special chemical and physical properties.
As a matter of fact, rare earth has been listed in the category
of strategic elements in many countries, such as the USA and Japan.
Some experts predict technological innovation
with the global development and application of rare earth.
What
is Rare Earth?
Rare
earth is a group of 17 elements including 15 lanthanides (La,
Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu) located
in the Periodical Table from atomic number 57 to 71, and Sc numbered
21 and Y numbered 39. According to the differences in chemical
and physical properties of rare earth elements, rare earth is
usually grouped into two subgroups: light rare earth or ceric
group including the first 7 lanthanides from La to Gd, and heavy
rare eath or yttric group including the rest of the lanthanides,
Sc and Y.
Rare
earth was first found by Finnish scientist Gadolin in 1794, and
he named it Rare Earth, thus leaving a misnomer for the group
of elements that is not earth at all, but a group of typical metallic
elements with chemical activity only next to alkaline and alkaline
earth metals. And rare earth is not rare at all, because the proven
reserves have reached 100 million tons REO. Based on its present
annual consumption (75,000 tons REO), the proven reserves of rare
earth can serve the world for over 1000 years.
Rare
earth exists in mineral forms in nature. The most commonly used
rare earth minerals are bastnasite, a kind of rare earth fluoro-carbonate,
and monazite, a kind of rare earth phosphate, and both minerals
are rich in light rare earth. Xenotime and ion-adsorption clay
minerals are the major source for heavy rare earth, and the ion-adsorption
clay minerals are only found in China. Up till now,
the world's largest deposit for light rare earth
is Baiyunebo deposit located in Baotou, Inner Mongolia, China.
Rare earth in the deposit coexists with iron and niobium and other
elements and is recovered as a byproduct of iron mining. Rare
earth concentrates with 50% to 65% REO are obtained by beneficiation,
but the concentrates can not be directly used, and must be processed
into rare earth chloride, carbonate or mischmetal which are called
primary products. Some of these products are used in traditional
industries such as metallurgy and chemical engineering, and most
of them are now processed into individual rare earth metals or
oxide for hi-tech applications.
The
unsaturated 4f electronic structure of rare earth elements makes
them have special properties of luminescence,
magnetism and electronics, which could be used to develop
many new materials, such as phosphors for TV's, lamps and X-rays,
magnetic and magnetostrictive materials, hydrogen storage materials
and auto-emission catalysts. Rare earth elements have been called
the treasure house of new materials in the 21st century.
Rare
Earth Resources
As
mentioned above, rare earth is not rare. The content of rare earth
in the Earth's crust is 0.0236%, much richer than many commonly
used elements such as Cu(0.01%), Zn(0.005%), Sn(0.004%), Pb(0.0016%)
and Ni(0.008%). The rich resources of rare earth are the strong
support to the development of hi-tech industries in the future.
The following lists the data for world's proven rare earth reserves,
reserve base and concentrate production in 1999.
| |
World |
China |
Baotou |
Baotou % of World |
Baotou % of China |
Reserves
(million tons REO) |
44.82 |
36.00 |
33.00 |
73.6
|
91.6
|
Reserve Base
(million tons REO) |
111.6 |
100.0 |
85.00 |
76
|
85
|
Concentrate
(tons REO) |
75000 |
66000 |
45000 |
60
|
68
|
Japan and Europe are the major consumers
of rare earth, but they do not possess rare earth resources.
Therefore, rare earth is largely an international
industry.
